Caffeine and green tea extract are in any diet pills that work at all, besides ephedrine and stuff like that which can mess you up. If it doesn't hurt your stomach, drinking a few cups of black coffee won't hurt you, the caffeine in coffee doesn't give me a buzz at all, however it helps me go to the bathroom which is awesome when you consume as much protein as I do, and protein can constipate you big time. To answer your original question, if you are sitting at a computer, caffeine will have a minimal effect on your metabolism, but if you use the "false energy" it gives you, than you can have a better workout which allows you to burn more calories. For example, today I had no energy at all, I had like 4 hours of sleep, so I drank a few diet mountain dews and it gave me a bit of a boost, I went to the gym and had an amazing workout. Without the caffeine I probably would have stayed home.