I really just think of the body in three main sections (shoulder girdle, legs, back). And I train them respectively with presses, squats, and pulls.
So for the shoulder girdle, I'd say Flat, Incline, or Decline bench with a barbell. it doesn't matter what one, I just pick one and train it consistently and progressively for at least 4 weeks at a time. With an angled press, I train an overhead lift, usually a behind the neck push or a standing push press, in the same cycle. (athletes can incorporate jerks or jerk presses, but for people with physique goals I don't see the need to do so).
For Legs, Back squats done ass to the grass and front squats ass to the grass.
For the back, deadlifts, barbell rows, shrugs done dynamically, olympic lifts and their various hybrids, and chins.
If I'm doing all that stuff right, then adding in bicep/tricep/calf work is pretty simple and elementary.........I just pick something tried and tru and non-retarded like barbell or dumbell or hammer curls for biceps.....skull crushers, push downs, or Tate presses for tries, and standing or seated calf raises. Some decline situps for abs, and that's about the extent of it.