Breakfast is arguably the most important meal of the day. You are coming off a long overnight fast and are fueling your body for the day. A protein shake is fine to consume for breakfast, but you also want to include in some high quality carbohydrates, some healthy fat and some fruits/vegeatbles.
What I would do is buy a high quality blender and blend together the following:
2 scoops of a high quality protein powder such as wheytobuildmuscle from n2bm.com
oatmeal
natural almond butter or peanut butter
frozen fruit
banana
ice
chia/flax seeds
spinach/kale
It'll be really nice tasting and be a much more complete breakfast.
I recommend having breakfast around 30-45 minutes after waking up. Wake up, drink 500mL of water, and then make your shake while you let the water digest. Once the shake is blended, have at it!